(2013•湖南)如图,在直棱柱ABCD-A1B1C1D1中,AD∥BC,∠BAD=90°,AC⊥BD,BC=1,AD=AA1=3.
(Ⅰ)证明:AC⊥B1D;
(Ⅱ)求直线B1C1与平面ACD1所成的角的正弦值.